Progress in Organosilicon Chemistry

Գրքի շապիկի երեսը
Bogdan Marciniec, Julian Chojnowski
Taylor & Francis, 1995 - 592 էջ
Progress in Organosilicon Chemistry comprises more than thirty papers presented by many of the world's most eminent organosilicon specialists at the Tenth International Symposium on Organosilicon Chemistry held in Poznan, Poland in August 1993. The conference marked the fiftieth anniversary of the discovery and exploration of "direct synthesis." As much attention today is directed beyond silicon polymers, chemists have become involved with the use of elementary silicon and its applications, including ultrapure silicon in transistors and computers, silicon precursors of polymers, and other silicon-based materials as well as fine chemicals. This book provides an overview of organosilicon chemistry, including organic and inorganic chemistry of silicon, silicon polymers and oligomers; theoretical and structural chemistry of silicon; silicon-based materials and their applications; silicon in organic synthesis; mechanistic organosilicon chemistry; and bio- and environmental organosilicon chemistry. This diverse range of topics makes the book a valuable reference for chemists working in both applied and theoretical chemistry.

From inside the book

Բովանդակություն

A Journey into the Chemical Country of Overloaded
19
Zwitterionic 5Organospirosilicates and 5Organo
55
The Structure and Properties of Hypervalent Silicon
69
AirStable 1Silaallenes
83
HydrogenRich Polysilylated Alkenes Alkynes
103
Synthesis and Reactivity of Small Cyclic Silicon Compounds
117
Synthesis and Characterization of Transition Metal Silylene
133
Substituent Constants of Groups at the Siatom
147
New Results in SbIII and BiIII HalideCatalyzed
325
Some New Silicotropic Rearrangements
345
Recent Achievements in Industrial Silicon Polymer Science
363
Formation of Silicon Oligomers and Polymers from
387
New Routes to Precursors for the Formation
411
Structural Control in Polysilanes Prepared by
429
Preparation of Organosilicon Oligomers and Polymers
445
A Molecular BuildingBlock Approach
467

Steric Factors in 29Si NMR Chemical Shifts
177
Coordination and Reactivity in Organosilicon Chemistry
191
The Chemistry of Functional Silyl Anions
209
The Stereochemistry of the S2 Reaction
223
Stereochemistry and Mechanism of Alcohol Addition
233
Frontier Orbital Control of Silylene Addition to Olefins
247
Recent Mechanism Studies on Hydrosilylation
263
Activation of SiX Bonds by ElectronDeficient
287
The Chemistry of 34Benzo1122tetraethyl1
309
Quantum Chemical Analysis and Prediction of Plasma
483
Condensation Vulcanizing Silicone Elastomers
503
Development and Application of Silicone Materials
523
Silicone Microemulsion Concentrates A New Approach
539
Recent Development of Metallurgical Silicon
555
Future Developments in Silicon Chemistry
571
Index
581
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