Progress in Organosilicon ChemistryBogdan Marciniec, Julian Chojnowski Taylor & Francis, 1995 - 592 էջ Progress in Organosilicon Chemistry comprises more than thirty papers presented by many of the world's most eminent organosilicon specialists at the Tenth International Symposium on Organosilicon Chemistry held in Poznan, Poland in August 1993. The conference marked the fiftieth anniversary of the discovery and exploration of "direct synthesis." As much attention today is directed beyond silicon polymers, chemists have become involved with the use of elementary silicon and its applications, including ultrapure silicon in transistors and computers, silicon precursors of polymers, and other silicon-based materials as well as fine chemicals. This book provides an overview of organosilicon chemistry, including organic and inorganic chemistry of silicon, silicon polymers and oligomers; theoretical and structural chemistry of silicon; silicon-based materials and their applications; silicon in organic synthesis; mechanistic organosilicon chemistry; and bio- and environmental organosilicon chemistry. This diverse range of topics makes the book a valuable reference for chemists working in both applied and theoretical chemistry. |
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A Journey into the Chemical Country of Overloaded | 19 |
Zwitterionic 5Organospirosilicates and 5Organo | 55 |
The Structure and Properties of Hypervalent Silicon | 69 |
AirStable 1Silaallenes | 83 |
HydrogenRich Polysilylated Alkenes Alkynes | 103 |
Synthesis and Reactivity of Small Cyclic Silicon Compounds | 117 |
Synthesis and Characterization of Transition Metal Silylene | 133 |
Substituent Constants of Groups at the Siatom | 147 |
New Results in SbIII and BiIII HalideCatalyzed | 325 |
Some New Silicotropic Rearrangements | 345 |
Recent Achievements in Industrial Silicon Polymer Science | 363 |
Formation of Silicon Oligomers and Polymers from | 387 |
New Routes to Precursors for the Formation | 411 |
Structural Control in Polysilanes Prepared by | 429 |
Preparation of Organosilicon Oligomers and Polymers | 445 |
A Molecular BuildingBlock Approach | 467 |
Steric Factors in 29Si NMR Chemical Shifts | 177 |
Coordination and Reactivity in Organosilicon Chemistry | 191 |
The Chemistry of Functional Silyl Anions | 209 |
The Stereochemistry of the S2 Reaction | 223 |
Stereochemistry and Mechanism of Alcohol Addition | 233 |
Frontier Orbital Control of Silylene Addition to Olefins | 247 |
Recent Mechanism Studies on Hydrosilylation | 263 |
Activation of SiX Bonds by ElectronDeficient | 287 |
The Chemistry of 34Benzo1122tetraethyl1 | 309 |
Quantum Chemical Analysis and Prediction of Plasma | 483 |
Condensation Vulcanizing Silicone Elastomers | 503 |
Development and Application of Silicone Materials | 523 |
Silicone Microemulsion Concentrates A New Approach | 539 |
Recent Development of Metallurgical Silicon | 555 |
Future Developments in Silicon Chemistry | 571 |
581 | |
Common terms and phrases
29Si NMR acid activation adduct alcohols Angew angle anion BiCl3 calculations carbon catalyst Chem chemical shifts chloride chlorosilanes cleavage condensation coordination correlation crystal cyclic dehydrocoupling derivatives disilane elastomers electron energy EXAFS FIGURE film formation formed furnace hydrogen hydrosilylation hypervalent intermediate intramolecular isomer J.Organomet kinetic ligands materials Me3Si mechanism metal metathesis methyl microemulsion mixture molecular weight molecules NMR spectra norbornene nucleophilic nucleophilic substitution observed obtained olefins oligomers orbital organic Organomet Organometallics Organosilicon Chemistry oxidative addition PCSZ pentacoordinate Ph Ph phenyl plasma CVD platinum polymerization polymers polysilanes polysiloxane precursors prepared presence properties proton ratio react reaction reactivity reductive elimination ring room temperature shown in Scheme Si-Si bond silanes silene silicates silicon atom silicon compounds silicone microemulsion silirane siloxanes silyl silyl group silylene SiMe3 solution solvent species stable steric effects structure substituents synthesis t-Bu thermal transition values X-ray yield zwitterionic