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brief account of an hypothesis of a somewhat similar nature, and stated himself to have developed this speculation in a Memoir which has not yet, so far as I am aware, been published. In this notice he conceives bodies to be compounded of molecules, which, arranged in a polyhedral form, constitute particles. These representative forms of the particles depend on chemical laws. Thus the particles of oxygen, of hydrogen, and of azote, are composed each of four molecules. Hence it is collected that the particles of nitrous gas are composed of two molecules of oxygen and two of azote; and similar conclusions are drawn respecting other substances. These conclusions, though expressed by means of the polyhedrons thus introduced, are supported by chemical, rather than by crystallographical comparisons. The author does, indeed, appeal to the crystallization of sal ammoniac as an argument*; but as all the forms which he introduces appear to belong to the tessular system of crystallization, there is, in his reasonings, nothing distinctive; and therefore nothing, crystallographically speaking, of any weight on the side of this theory.

8. Any hypothesis which should introduce any principle of chemical order among the actual forms of minerals, would well deserve attention. At first sight, nothing can appear more anomalous than the forms which occur. We have, indeed, one broad fact, which has an encouraging aspect, the tessular forms in which the pure metals crystallize. The highest degree of chemical and of geometrical simplicity coincide: irregularity disappears precisely where it is excluded by the consideration above stated, that the symmetry of chemical composition must determine the symmetry of crystalline

form*

* Ann. de Chimie, tom. xc. p. 83.

✦ Inasmuch as this law, that the simple metals crystallize in tes

But if we go on to any other class of crystalline forms, we soon find ourselves lost in our attempts to follow any thread of order. We have indeed many large groups connected by obvious analogies; as the rhombohedral carbonates of lime, magnesia, iron, manganese;the prismatic carbonates and sulphates of lime, baryta, strontia, lead. But even in these, we cannot form any plausible hypothesis of the arrangement of the elements; and in other cases to which we naturally turn, we can find nothing but confusion. For instance, if we examine the oxides of metals:-those of iron are rhombohedral and tessular; those of copper, tessular; those of tin, of titanium, of manganese, square pyramidal; those of antimony, prismatic; and we have other forms for other substances.

It may be added, that if we take account of the

sular forms, is the most signal example of that connexion between the chemical nature of a body and its crystalline form, I in the former Edition stated it with as much generality as I could find any ground for, and I should have been glad if I could have added confirmation of the law, derived from later observations. But the most recent investigations of crystallographers appear to have afforded exceptions rather than examples of the rule. Arsenic and Tellurium are said to be rhom bohedral. Antimony, stated by Haüy to be octahedral (and therefore tessular), has been found by more modern observers to be rhombohedral. Tin has been obtained by Professor Miller in beautiful crystals belonging to the pyramidal system. Professor Nöggerath has observed in Zinc, after cooling from fusion, hexagonal cleavage, rendering it probable that the mineral crystallized in rhombohedrons having their axes vertical, like ice. G. Rose conceives it highly probable that Osmium and Iridium are rhombohedral. (Poggendorf. Bd. LIV.)

But all the more perfect metals are tessular; namely, Gold, Silver, Mercury, Platinum, Iron, Copper; also Bismuth. Perhaps the observation in which the crystallization of Zinc is affected by its position is, on that very account, no sufficient evidence of its free crystallization. We can hardly conceive a collection of perfectly simple, similar particles to crystallize so as to have one pre-eminent axis, without some extraneous action affecting them.

optical properties which, as we have already stated, have constant relations to the crystalline forms, the confusion is still further increased; for the optical dimensions vary in amount, though not in symmetry, where chemistry can trace no difference of composition.

9. We will not quit the subject, however, without noticing the much more promising aspect which it has assumed by the detection of such groups as are referred to in the last article; or in other words, by Mitscherlich's discovery of Isomorphism. According to that discovery, there are various elements which may take the place of each other in crystalline bodies, either without any alteration of the crystalline form, or at most with only a slight alteration of its dimensions. Such a group of elements we have in the earths lime and magnesia, the protoxides of iron and manganese: for the carbonates of all these bases occur crystallized in forms of the rhombohedral system, the characteristic angle being nearly the same in all. Now lime and magnesia, by the discoveries of modern chemistry, are really oxides of metals; and therefore all these carbonates have a similar chemical constitution, while they have also a similar crystalline form. Whether or no we can devise any arrangement of molecules by which this connexion of the chemical and the geometrical property can be represented, we cannot help considering the connexion as an extremely important fact in the constitution of bodies; and such facts are more likely than any other to give us some intelligible view of the relations of the ultimate parts of bodies. The same may be said of all the other isomorphous or plesiomorphous groups*. For instance, we have a number of minerals which belong to the same system of crystallization, but in which the chemical composition appears at first sight to be very various: *See Hist. Ind. Sci., B. xv. c. vi.

namely, spinelle, pleonaste, gahnite, franklinite, chromic iron oxide, magnetic iron oxide: but Abich has shown that all these may be reduced to a common chemical formula;-they are bioxides of one set of bases, combined with trioxides of another set. Perhaps some mathematician may be able to devise some geometrical arrangement of such a group of elements which may possess the properties of the tessular system. Hypothetical arrangements of atoms, thus expressing both the chemical and the crystalline symmetry which we know to belong to the substance, would be valuable steps in analytical science; and when they had been duly verified, the hypotheses might easily be divested of their atomic character.

Thus, as we have already said, mineralogy, understood in its wider sense, as the counterpart of chemistry, has for one of its main objects to discover those relations of the elements of bodies which have reference to space. In this research, the foundation of all sound speculation is the kind and degree of symmetry of form which we find in definite chemical compounds: and the problem at present before the inquirer is, to devise such arrangements of molecules as shall answer the conditions alike of chemistry and of crystallography.

We now proceed to the Classificatory Sciences, of which Mineralogy is one, though hitherto by far the least successful.

VOL. I. W. P.

Нн

466

BOOK VIII.

THE PHILOSOPHY OF THE CLASSIFI
CATORY SCIENCES.

CHAPTER I.

THE IDEA OF LIKENESS AS GOVERNING THE USE OF COMMON NAMES.

1. Object of the Chapter.—NOT only the Classificatory Sciences, but the application of names to things in the rudest and most unscientific manner, depends upon our apprehending them as like each other. We must therefore endeavour to trace the influence and operation of the Idea of Likeness in the common use of language, before we speak of the conditions under which it acquires its utmost exactness and efficacy.

It will be my object to show in this, as in previous cases, that the impressions of sense are apprehended by acts of the mind; and that these mental acts necessarily imply certain relations which may be made the subjects of speculative reasoning. We shall have, if we can, to seize and bring into clear view the principles which the relation of like and unlike involves, and the mode in which these principles have been developed.

2. Unity of the Individual.-But before we can attend to several things as like or unlike, we must be able to apprehend each of these by itself as one thing. It may at first sight perhaps appear that this apprehension results immediately from the impressions on our senses, without

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