Organic ChemistryThomson-Brooks/Cole, 2004 - 1176 էջ John McMurry's international best-seller is widely and consistently praised as the most clearly written book on the market. Why? In John McMurry's words: "I have been asked hundreds of times over the past ten years why I wrote this book. I wrote this book because I love writing. I get great pleasure and satisfaction from taking a complicated subject, turning it around until I see it clearly from a new angle, and then explaining it in simple words. I write to explain chemistry to students the way I wish it had been explained to me years ago." Through his lucid writing and ability to show the beauty and logic of organic chemistry, McMurry makes learning enjoyable for students. The highest compliment that can be given to a chemistry book applies to McMurry: It works! Mainstream in level, McMurry's coverage is concise yet doesn't omit any key topics. McMurry blends the traditional functional-group approach with a mechanistic approach. The primary approach, by functional group, begins with the simple and progresses to the more complex so that readers who are not yet versed in the subtleties of mechanisms are first exposed to the "what" of chemistry before beginning to grapple with the "why." Within this primary organization, the author places a heavy emphasis on explaining the fundamental mechanistic similarities. In this edition, McMurry retains his standard-setting features (including his innovative vertical format for explaining reaction mechanisms) while revising his text line-by-line to include hundreds of small but important improvements. For example, the Sixth Edition includes new examples, additional steps in existing examples, new problems, new phrases to clarify the exposition, and a vibrant new art program. In addition, new icons in the text lead students to a variety of new online resources. McMurry's text is in use at hundreds of colleges and universities around the world, from North America, to the United Kingdom and the Pacific Rim. |
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Brief Contents 1 Structure and Bonding | 1 |
2 | 21 |
Polar Covalent Bonds Acids and Bases | 29 |
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Common terms and phrases
13C NMR ¹H NMR absorption acetic acyl addition reactions alcohol aldehyde aldol alkane alkene alkyl halide alkyne amine anion aromatic ring base benzene bromination C-H bond carbocation intermediate carbon atom carbonyl carbonyl compound carbonyl group carboxylic acid catalyst CH₂OH CH3 CH3 CH3 H Chemical shift chirality center Click Organic Interactive CO₂H conjugated cyclohexane double bond Draw electrons electrophilic enantiomer energy enolate ion ester ethanol ether ethylene example following compounds functional groups Grignard reagent H CH3 H H H H&C H H₂O H3O+ halogen hydrogen isomers IUPAC kcal/mol ketone kJ/mol leaving group LiAlH4 methyl molecular molecule NaOH nitrile nitrogen NMR spectrum nucleophilic acyl substitution nucleophilic addition occurs orbitals Organic Chemistry Organic Chemistry Direct oxidation oxygen phenol polar PROBLEM protons radical react reactant reactive Section shown in Figure SN2 reaction solvent spectroscopy stable step stereochemistry structure substitution reactions synthesis tertiary tetrahedral tion yield